Catalysis with Palladium Complexes Photoexcited by Visible Light

Padon Chuentragool, Daria Kurandina, Vladimir Gevorgyan

Research output: Contribution to journalReview article

19 Scopus citations

Abstract

Palladium catalysis induced by visible light is an emerging field of catalysis. In contrast to classical reactions catalyzed by Pd complexes in the ground state, which mostly proceed through two-electron redox processes, the mechanisms of these new methods based on photoexcited Pd complexes usually operate through transfer of a single electron. Such processes lead to putative hybrid Pd/radical species, which exhibit both radical and classical Pd-type reactivity. This Minireview highlights the recent progress in this rapidly growing area.

Original languageEnglish (US)
Pages (from-to)11586-11598
Number of pages13
JournalAngewandte Chemie - International Edition
Volume58
Issue number34
DOIs
StatePublished - 2019

Keywords

  • excited-state Pd complex
  • palladium
  • photochemistry
  • radical reactions

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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