Chemodivergent transformations of alkynyl imines

Anna W. Sromek; Arnold L. Rheingold; Donald J. Wink; Vladimir Gevorgyan

doi:10.1055/s-2006-949652

Chemodivergent transformations of alkynyl imines

Anna W. Sromek, Arnold L. Rheingold, Donald J. Wink, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The investigation of cycloisomerization cascades of alkynyl imines towards pyrroles unexpectedly led to the development of chemodivergent routes towards quinolines and fused pyrrolines. It was found that, depending on the nature of the nitrogen substituent and choice of reagents, up to three different heterocyclic cores can be accessed from a common structural precursor.

Original language	English (US)
Pages (from-to)	2325-2328
Number of pages	4
Journal	Synlett
Issue number	14
DOIs	https://doi.org/10.1055/s-2006-949652
State	Published - Sep 1 2006
Externally published	Yes

Keywords

Alkynyl imines
Cycloaddition
Electrophilic cyclization
Heterocycles
Quinoline

ASJC Scopus subject areas

Organic Chemistry

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abstract = "The investigation of cycloisomerization cascades of alkynyl imines towards pyrroles unexpectedly led to the development of chemodivergent routes towards quinolines and fused pyrrolines. It was found that, depending on the nature of the nitrogen substituent and choice of reagents, up to three different heterocyclic cores can be accessed from a common structural precursor.",

keywords = "Alkynyl imines, Cycloaddition, Electrophilic cyclization, Heterocycles, Quinoline",

author = "Sromek, {Anna W.} and Rheingold, {Arnold L.} and Wink, {Donald J.} and Vladimir Gevorgyan",

year = "2006",

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AU - Rheingold, Arnold L.

AU - Wink, Donald J.

AU - Gevorgyan, Vladimir

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AB - The investigation of cycloisomerization cascades of alkynyl imines towards pyrroles unexpectedly led to the development of chemodivergent routes towards quinolines and fused pyrrolines. It was found that, depending on the nature of the nitrogen substituent and choice of reagents, up to three different heterocyclic cores can be accessed from a common structural precursor.

KW - Alkynyl imines

KW - Cycloaddition

KW - Electrophilic cyclization

KW - Heterocycles

KW - Quinoline

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ER -

Chemodivergent transformations of alkynyl imines

Abstract

Keywords

ASJC Scopus subject areas

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