Crystal and molecular structure of hexa(antipyrine)cadmium(II) Perchlorate, [(C11H12ON2)6CD]2+ [FORMULA OMITTED]

C. Mahadevan, Akella Radha, M. Seshasayee

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

The crystal and molecular structure of the title compound is reported. Crystals are trigonal with hexagonal axes, space group P3 with Z = 1 in a unit cell of dimensions a = b= 14.196(7) and c = 9.558(5) Ǻ. The structure was solved by the heavy-atom method and refined by the full-matix least-squares method to R = 0.071 for 1097 unique reflections. The metal atom of the cation has a regular octahedral configuration and the chlorine atoms of the anions have regular tetrahedral configuration. Both the five-and six-membered rings in the antipyrine are planar having an angle of 113° between the normals to their planes.

Original languageEnglish (US)
Pages (from-to)159-163
Number of pages5
JournalZeitschrift fur Kristallographie - New Crystal Structures
Volume169
Issue number1-4
DOIs
StatePublished - Jan 1 1984

Keywords

  • Crystal structure
  • Hexa(antipyrine)cadmium(II) Perchlorate

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

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