Crystal and molecular structure of hexa(antipyrine)cadmium(II) Perchlorate, [(C11H12ON2)6CD]2+ [FORMULA OMITTED]

C. Mahadevan, Akella Radha, M. Seshasayee

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The crystal and molecular structure of the title compound is reported. Crystals are trigonal with hexagonal axes, space group P3 with Z = 1 in a unit cell of dimensions a = b= 14.196(7) and c = 9.558(5) Ǻ. The structure was solved by the heavy-atom method and refined by the full-matix least-squares method to R = 0.071 for 1097 unique reflections. The metal atom of the cation has a regular octahedral configuration and the chlorine atoms of the anions have regular tetrahedral configuration. Both the five-and six-membered rings in the antipyrine are planar having an angle of 113° between the normals to their planes.

Original languageEnglish (US)
Pages (from-to)159-163
Number of pages5
JournalZeitschrift fur Kristallographie - New Crystal Structures
Volume169
Issue number1-4
DOIs
StatePublished - 1984

Fingerprint

Antipyrine
perchlorates
Cadmium
cadmium
Molecular structure
molecular structure
Crystal structure
Atoms
crystal structure
atoms
Chlorine
least squares method
configurations
Anions
chlorine
Cations
Negative ions
Positive ions
Metals
anions

Keywords

  • Crystal structure
  • Hexa(antipyrine)cadmium(II) Perchlorate

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

Crystal and molecular structure of hexa(antipyrine)cadmium(II) Perchlorate, [(C11H12ON2)6CD]2+ [FORMULA OMITTED]. / Mahadevan, C.; Radha, Akella; Seshasayee, M.

In: Zeitschrift fur Kristallographie - New Crystal Structures, Vol. 169, No. 1-4, 1984, p. 159-163.

Research output: Contribution to journalArticle

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