Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: Efficient synthesis of indolizines

V. Helan; A. V. Gulevich; V. Gevorgyan

doi:10.1039/c4sc03358b

Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: Efficient synthesis of indolizines

V. Helan, A. V. Gulevich, V. Gevorgyan

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138 Scopus citations

Abstract

A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.

Original language	English (US)
Pages (from-to)	1928-1931
Number of pages	4
Journal	Chemical Science
Volume	6
Issue number	3
DOIs	https://doi.org/10.1039/c4sc03358b
State	Published - Mar 1 2015
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: Efficient synthesis of indolizines",

abstract = "A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.",

author = "V. Helan and Gulevich, {A. V.} and V. Gevorgyan",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

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doi = "10.1039/c4sc03358b",

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T1 - Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions

T2 - Efficient synthesis of indolizines

AU - Helan, V.

AU - Gulevich, A. V.

AU - Gevorgyan, V.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.

AB - A Cu(i)-catalyzed denitrogenative transannulation reaction of pyridotriazoles with terminal alkynes en route to indolizines was developed. Compared to the previously reported Rh-catalyzed transannulation reaction, this Cu-catalyzed method features aerobic conditions and a much broader scope of pyridotriazoles and alkynes.

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U2 - 10.1039/c4sc03358b

DO - 10.1039/c4sc03358b

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JF - Chemical Science

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Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: Efficient synthesis of indolizines

Abstract

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