Environmentally benign perfluorooctanesulfonate alternatives using a Zn/CuI mediated Michael-type addition in imidazolium ionic liquids

B. V D Vijaykumar; B. Premkumar; Kiwan Jang; Bong In Choi; J R Falck; G. N. Sheldrake; Dong Soo Shin

doi:10.1039/c3gc42642d

Environmentally benign perfluorooctanesulfonate alternatives using a Zn/CuI mediated Michael-type addition in imidazolium ionic liquids

B. V D Vijaykumar, B. Premkumar, Kiwan Jang, Bong In Choi, J R Falck, G. N. Sheldrake, Dong Soo Shin

Biochemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The design and synthesis of hemi-fluorinated perfluorooctanesulfonic acid (PFOS) alternatives is described using a Zn/CuI mediated Michael-type addition reaction in ionic liquids considering environmentally benign reaction conditions as well as products. One of the new potassium sulfonates showed promising surface tension activities when compared to that of the PFOS potassium salt.

Original language	English (US)
Pages (from-to)	2406-2410
Number of pages	5
Journal	Green Chemistry
Volume	16
Issue number	5
DOIs	https://doi.org/10.1039/c3gc42642d
State	Published - May 2014

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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abstract = "The design and synthesis of hemi-fluorinated perfluorooctanesulfonic acid (PFOS) alternatives is described using a Zn/CuI mediated Michael-type addition reaction in ionic liquids considering environmentally benign reaction conditions as well as products. One of the new potassium sulfonates showed promising surface tension activities when compared to that of the PFOS potassium salt.",

author = "Vijaykumar, {B. V D} and B. Premkumar and Kiwan Jang and Choi, {Bong In} and Falck, {J R} and Sheldrake, {G. N.} and Shin, {Dong Soo}",

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AU - Vijaykumar, B. V D

AU - Premkumar, B.

AU - Jang, Kiwan

AU - Choi, Bong In

AU - Falck, J R

AU - Sheldrake, G. N.

AU - Shin, Dong Soo

PY - 2014/5

Y1 - 2014/5

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AB - The design and synthesis of hemi-fluorinated perfluorooctanesulfonic acid (PFOS) alternatives is described using a Zn/CuI mediated Michael-type addition reaction in ionic liquids considering environmentally benign reaction conditions as well as products. One of the new potassium sulfonates showed promising surface tension activities when compared to that of the PFOS potassium salt.

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Environmentally benign perfluorooctanesulfonate alternatives using a Zn/CuI mediated Michael-type addition in imidazolium ionic liquids

Abstract

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