Phase-transfer catalysis in reduction by lithium aluminium hydride

Vladimir Gevorgyan; Edmunds Lukevics

doi:10.1039/c39850001234

Phase-transfer catalysis in reduction by lithium aluminium hydride

Vladimir Gevorgyan, Edmunds Lukevics

Research output: Contribution to journal › Article

14 Scopus citations

Abstract

Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH₄-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

Original language	English (US)
Pages (from-to)	1234-1235
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/c39850001234
Publication status	Published - Jan 1 1985
Externally published	Yes

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ASJC Scopus subject areas

Molecular Medicine

Cite this

Gevorgyan, V., & Lukevics, E. (1985). Phase-transfer catalysis in reduction by lithium aluminium hydride. Journal of the Chemical Society, Chemical Communications, (18), 1234-1235. https://doi.org/10.1039/c39850001234

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abstract = "Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.",

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AU - Lukevics, Edmunds

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N2 - Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

AB - Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

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Access to Document

10.1039/c39850001234