Phase-transfer catalysis in reduction by lithium aluminium hydride

Vladimir Gevorgyan; Edmunds Lukevics

doi:10.1039/c39850001234

Phase-transfer catalysis in reduction by lithium aluminium hydride

Vladimir Gevorgyan, Edmunds Lukevics

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH₄-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

Original language	English (US)
Pages (from-to)	1234-1235
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/c39850001234
State	Published - Jan 1 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Phase-transfer catalysis in reduction by lithium aluminium hydride",

abstract = "Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.",

author = "Vladimir Gevorgyan and Edmunds Lukevics",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/c39850001234",

language = "English (US)",

pages = "1234--1235",

journal = "Chemical Communications",

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T1 - Phase-transfer catalysis in reduction by lithium aluminium hydride

AU - Gevorgyan, Vladimir

AU - Lukevics, Edmunds

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

AB - Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), the reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.

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