Removal of sulfur groups from molecules by copper(I). Preparation of sulfur-substituted 1,3-dienes for the Diels-Alder reaction

Theodore Cohen, Albert J. Mura, David W. Shull, Elaine R. Fogel, Robert J. Ruffner, J R Falck

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

The elimination of thiophenol by copper(I) from readily prepared precursors leads in good yield to several useful phenylthio-subtituted Diels-Alder dienes including (Z)-1-phenylthio-2-methoxy-1,3-butadiene which yields a m-methoxy adduct with methyl vinyl ketone.

Original languageEnglish (US)
Pages (from-to)3218-3219
Number of pages2
JournalJournal of Organic Chemistry
Volume41
Issue number19
StatePublished - 1976

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Sulfur
Copper
Molecules
thiophenol
3-buten-2-one
2-methoxy-1,3-butadiene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Removal of sulfur groups from molecules by copper(I). Preparation of sulfur-substituted 1,3-dienes for the Diels-Alder reaction. / Cohen, Theodore; Mura, Albert J.; Shull, David W.; Fogel, Elaine R.; Ruffner, Robert J.; Falck, J R.

In: Journal of Organic Chemistry, Vol. 41, No. 19, 1976, p. 3218-3219.

Research output: Contribution to journalArticle

Cohen, Theodore ; Mura, Albert J. ; Shull, David W. ; Fogel, Elaine R. ; Ruffner, Robert J. ; Falck, J R. / Removal of sulfur groups from molecules by copper(I). Preparation of sulfur-substituted 1,3-dienes for the Diels-Alder reaction. In: Journal of Organic Chemistry. 1976 ; Vol. 41, No. 19. pp. 3218-3219.
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