Stereoselective [2,3]-rearrangements of amine N -oxides

Hongli Bao, Xiangbing Qi, Uttam K. Tambar

Research output: Contribution to journalArticle

17 Scopus citations

Abstract

Despite the long history of [2,3]-sigmatropic rearrangements, there are surprisingly few catalytic and enantioselective variants of these transformations. This article describes the most common strategies developed for stereoselective [2,3]-rearrangements of amine N-oxides (Meisenheimer rearrangement), including our recently reported palladium-catalyzed enantioselective process.

Original languageEnglish (US)
Pages (from-to)1789-1792
Number of pages4
JournalSynlett
Issue number13
DOIs
StatePublished - Jul 22 2011

Keywords

  • amine N -oxide
  • asymmetric catalysis
  • palladium
  • pericyclic reaction
  • rearrangement

ASJC Scopus subject areas

  • Organic Chemistry

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