Abstract
(Chemical Equation Presented) Functionalized salicylates in a flash: Photolysis of functionalized benzodioxinones in the presence of alcohols or amines is a powerful method for the synthesis of sterically hindered salicylic esters and amides (see scheme). This reaction tolerates a broad range of functional groups and efficiently engages a wide range of acylation substrates, including sterically hindered nucleophiles that are inert to other acylation methods.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1696-1699 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 44 |
| Issue number | 11 |
| DOIs | |
| State | Published - Mar 4 2005 |
Keywords
- Acylation
- Natural products
- Photochemistry
- Synthetic methods
ASJC Scopus subject areas
- Catalysis
- General Chemistry