Abstract
Dichlorocarbene generated in a two-phase catalytic system reacts with 3-trimethylsilyl-2,5-dihydrofuran to give both possible products of mono-insertion into the CH bond in positions 2 and 5 of the ring, together with a CC bond adduct. Reaction of 2-trimethylsilyl-4,5-dihydrofuran with dichlorocarbene leads to 2,3-dichloro-2-trimethylsilyl-5,6-dihydro-2H-pyran, which is formed via isomerization of the primary bicyclic adduct.
Original language | English (US) |
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Pages (from-to) | 237-240 |
Number of pages | 4 |
Journal | Journal of Organometallic Chemistry |
Volume | 265 |
Issue number | 3 |
DOIs | |
State | Published - Apr 17 1984 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry