The interaction of dihydrofurylsilanes with dichlorocarbene under phase-transfer conditions

E. Lukevics, V. N. Gevorgyan, Y. S. Goldberg, A. P. Gaukhman, M. P. Gavars, J. J. Popelis, M. V. Shymanska

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

Dichlorocarbene generated in a two-phase catalytic system reacts with 3-trimethylsilyl-2,5-dihydrofuran to give both possible products of mono-insertion into the CH bond in positions 2 and 5 of the ring, together with a CC bond adduct. Reaction of 2-trimethylsilyl-4,5-dihydrofuran with dichlorocarbene leads to 2,3-dichloro-2-trimethylsilyl-5,6-dihydro-2H-pyran, which is formed via isomerization of the primary bicyclic adduct.

Original languageEnglish (US)
Pages (from-to)237-240
Number of pages4
JournalJournal of Organometallic Chemistry
Volume265
Issue number3
DOIs
StatePublished - Apr 17 1984
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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    Lukevics, E., Gevorgyan, V. N., Goldberg, Y. S., Gaukhman, A. P., Gavars, M. P., Popelis, J. J., & Shymanska, M. V. (1984). The interaction of dihydrofurylsilanes with dichlorocarbene under phase-transfer conditions. Journal of Organometallic Chemistry, 265(3), 237-240. https://doi.org/10.1016/0022-328X(84)80086-8